Vol. 1 No. 3 (2025): December
Open Access
Peer Reviewed

Characterization of Photocurable Functionalized-CNT Nanocoating to Mitigate the Naturally Emission of Radon Gas

Authors

Aisha Dalila Ab Aziz , Mohd Hamzah Harun , Izzuddin Mohamad Zaharuddin , Nor Adnin Ezani Mohd Ezani , Norfazlinayati Othman , Mahathir Mohamed , Mohd Sofian Alias , Mohd Faizal Abd Rahman , Khairil Nor Kamal Umar , Nurul Huda Mudri , Khairul Azhar Abdul Halim , Mohamad Syahiran Mustafa , Lakam Mejus , Faizal Azrin Abdul Razalim , Rosley Che Ismail , Abdul Muiz Mohd Sani , Sharilla Mohd Faisal , Rida Tajau

DOI:

10.56566/jmsr.v1i3.480

Downloads

Received: 2025-10-24
Accepted: 2025-12-26
Published: 2025-12-27

Abstract

This study focuses on the synthesis and characterization of an anti-radon photocurable nanocoating formulated using a UV-curable formulation incorporated with functionalized carbon nanotubes (F-CNTs). The coating was prepared using Ebecryl 600 (urethane acrylate oligomer) and TMPTA (monomer), with GPTMS as a coupling agent and various photoinitiator combinations. Different F-CNT loadings ranging from 0.1 to 0.9 wt% were studied to evaluate their effects on coating performance. The samples were cured under UV irradiation for 2–20 passes to investigate the influence of exposure time on polymer crosslinking. Characterization analyses including pendulum hardness, Fourier-transform infrared spectroscopy (FTIR), viscosity, gel content, and radon gas permeability were performed. Results indicated that the incorporation of F-CNTs enhanced the mechanical strength and crosslinking density of the coating. The optimal formulation exhibited a hardness of 150.33 s (BAPO + 8 passes) and a gel content of 97%. Furthermore, radon concentration measurements showed a 28.9% reduction after applying a single coating layer, confirming the coating’s potential as an effective barrier for radon gas mitigation.

Keywords:

Anti-radon coating Functionalized carbon nanotubes Photocurable nanocoating UV-curable polymer

References

Ahmad, N., Khan, I. U., Rehman, J., & Nasir, T. (2017). An overview of radon concentration in Malaysia. Journal of Radiation Research And Applied Sciences, 10(4), 327-330. https://doi.org/10.1016/j.jrras.2017.08.001 DOI: https://doi.org/10.1016/j.jrras.2017.08.001

Alias, M. S., Othman, N. K., Kamarudin, S. R. M., Harun, M. H., Mohamed, M., Saidin, N. U., Mohamad, S. F. & Samsu, Z. (2022). Influence of graphite particles in UV-curable corrosion protection coating from palm oil based urethane acrylate (POBUA). Industrial Crops and Products, 187, 115436. https://doi.org/10.1016/j.indcrop.2022.115436 DOI: https://doi.org/10.1016/j.indcrop.2022.115436

Alias, M. S., Zulkafli, R., Othman, N. K., Jamil, M. S. M., Kamarudin, S. R. M., Mohamad, S. F., Harun, M. H. & Mohamed, M. (2025). Improving Corrosion Protection of Urethane Acrylate UV Curable Coatings Derived from Palm Oil via Graphene Oxide Particle Incorporation. Sains Malaysiana, 54(2), 589-599. DOI: https://doi.org/10.17576/jsm-2025-5402-23

Barnes, H. A. (2001). An examination of the use of rotational viscometers for the quality control of non-Newtonian liquid products in factories. Applied Rheology, 11(2), 70-101. https://doi:10.1515/arh-2001-0006 DOI: https://doi.org/10.1515/arh-2001-0006

Bezek, L. B., & Williams, C. B. (2023). Process-structure-property effects of ultraviolet curing in multi-material jetting additive manufacturing. Additive Manufacturing, 73, 103640. https://doi.org/10.1016/j.addma.2023.103640 DOI: https://doi.org/10.1016/j.addma.2023.103640

Cofone, L., Sabato, M., Colombo, C., Scalingi, S., Montesi, A., Paglione, L., & Patania, F. (2025). Health Effects and Preventive Strategies for Radon Exposure: A Systematic Review of the Literature. Journal of Respiration, 5(4), 16. https://doi.org/10.3390/jor5040016 DOI: https://doi.org/10.3390/jor5040016

Crivello, J. V., & Bulut, U. (2005). Radiation curable coatings and inks containing nanomaterials. Progress in Organic Coatings, 52(2), 109–120. https://doi.org/10.1016/j.porgcoat.2004.11.001 DOI: https://doi.org/10.1016/j.porgcoat.2004.11.001

Cunningham, A. F., Desobry, V., Dietliker, K., Hüsler, R., & Leppard, D. G. (1994). Recent developments in radical photoinitiator chemistry. Chimia, 48(9), 423-423. DOI: https://doi.org/10.2533/chimia.1994.423

Decker, C. (2002). Kinetic study and new applications of UV radiation curing. Macromolecular Rapid Communications, 23(18), 1067–1093. https://doi.org/10.1002/marc.200290012 DOI: https://doi.org/10.1002/marc.200290014

Diekmann, A., Omelan, M. C., & Giese, U. (2021). Influence of carbon nanotube-pretreatment on the properties of polydimethylsiloxane/carbon nanotube-nanocomposites. Polymers, 13(9), 1355. https://doi.org/10.3390/polym13091355 DOI: https://doi.org/10.3390/polym13091355

Dose, M. (2016). Reducing Radon Gas Emission in Concrete (Phd. thesis). KTH Royal Institute of Technology, Stockholm, Sweden.

Harun, M. H., Salleh, N. G. N., Alias, M. S., Mohamed, M., Abdul Rahman, M. F., Hamzah, M. Y. & Othman, N. (2018). Removal of Oxidative Debris from Chemically Functionalized Multi-walled Carbon Nanotube (MWCNT). International Journal of Nanoelectronics & Materials, 11(1). https://ijneam.unimap.edu.my/images/PDF/IJNEAM%20No.%201%202018%20JAN/Vol_11_No_1_2018_5_43-48.pdf

Harun, M. H. (2017). Carbon Nanotubes and Radiation Applications in its Synthesis. Chapter 7. Ionizing Radiation Processing Technology (pp. 153-169), Malaysian Nuclear Agency.

Hossain, M. M., Chowdhury, H. I., Siddiqui, M. S., Hossain, M. S., & Rabbi, M. S. (2025). Recent Advances in Coated Carbon Nanotube-Reinforced Metal Matrix Composites: Challenges, Techniques, and Performance Enhancement. Carbon Trends, 100568, 1-36. https://doi.org/10.1016/j.cartre.2025.100568 DOI: https://doi.org/10.1016/j.cartre.2025.100568

Hsissou, R., Bekhta, A., Dagdag, O., El Bachiri, A., Rafik, M., & Elharfi, A. (2020). Rheological properties of composite polymers and hybrid nanocomposites. Heliyon, 6(6)

https://doi:10.1016/j.heliyon.2020.e04187 DOI: https://doi.org/10.1016/j.heliyon.2020.e04187

Huang, P., Lv, W., Huang, R., Feng, Y., Luo, Q., Yin, C., & Yang, Y. (2024). Impact of environmental factors on atmospheric radon variations at China Jinping Underground Laboratory. Scientific Reports, 14(1), 31402. https://doi:10.1038/s41598-024-82936-0 DOI: https://doi.org/10.1038/s41598-024-82936-0

Jena, K. K., & Raju, K. S. N. (2008). Synthesis and characterization of hyperbranched polyurethane hybrids using tetraethoxysilane (TEOS) as cross-linker. Industrial & Engineering Chemistry Research, 47(23), 9214-9224. https://0.1021/ie800884y DOI: https://doi.org/10.1021/ie800884y

Kang, J. K., Seo, S., & Jin, Y. W. (2019). Health effects of radon exposure. Yonsei Medical Journal, 60(7), 597-603. https://doi.org/10.3349/ymj.2019.60.7.597 DOI: https://doi.org/10.3349/ymj.2019.60.7.597

Kashkinbayev, Y., Kazhiyakhmetova, B., Altaeva, N., Bakhtin, M., Tarlykov, P., Saifulina, E., Aumalikova, M., Ibrayeva, D., & Bolatov, A. (2025). Radon Exposure and Cancer Risk: Assessing Genetic and Protein Markers in Affected Populations. Biology, 14(5), 506. https://doi.org/10.3390/biology14050506 DOI: https://doi.org/10.3390/biology14050506

Kellenbenz, K. R., & Shakya, K. M. (2021). Spatial and temporal variations in indoor radon concentrations in Pennsylvania, USA from 1988 to 2018. Journal of Environmental Radioactivity, 233, 106594. https://doi.org/10.1016/j.jenvrad.2021.106594 DOI: https://doi.org/10.1016/j.jenvrad.2021.106594

Khoswan, I., Abusafa, A., & Odeh, S. (2024). The effect of carbon nanotubes on the viscosity and surface tension of heat transfer fluids—A review paper. Energies, 17(22), 5584. https://doi.org/10.3390/en17225584 DOI: https://doi.org/10.3390/en17225584

Kim, S. H., Lee, K. H., Kim, D. H., Kim, M. J., Jung, K. S., & Cho, S. Y. (2012). Radon mitigation efficiency using nano-size carbon colloid. Technical Proceedings of the 2012 NSTI Nanotechnology Conference and Expo, NANOTech 2012 Volumes 1, 433-436.

Kotsilkova, R., & Tabakova, S. (2023). Exploring effects of graphene and carbon nanotubes on rheology and flow instability for designing printable polymer nanocomposites. Nanomaterials, 13(5), 835. https://doi.org/10.3390/nano13050835 DOI: https://doi.org/10.3390/nano13050835

Li, H., Li, Z., Qiu, L., Dong, S., Ouyang, J., Dong, X., & Han, B. (2023). Rheological behaviors and viscosity prediction model of cementitious composites with various carbon nanotubes. Construction and Building Materials, 379, 131214. https://doi.org/10.1016/j.conbuildmat.2023.131214 DOI: https://doi.org/10.1016/j.conbuildmat.2023.131214

Liu, Y., Fu, C., Li, Y., Xu, W., Huang, Z., & Xu, Y. (2025). Uncovering hidden dangers in urban housing: Sources of indoor radon and associated health risks. Journal of Environmental Management, 387, 125899. https://doi.org/10.1016/j.jenvman.2025.125899 DOI: https://doi.org/10.1016/j.jenvman.2025.125899

Mphaga, K. V., Mbonane, T. P., Utembe, W., & Rathebe, P. C. (2024). Short-Term vs. Long-Term: A Critical Review of Indoor Radon Measurement Techniques. Sensors, 24(14), 4575. https://doi.org/10.3390/s24144575 DOI: https://doi.org/10.3390/s24144575

Park, S., & Kim, H. (2021). Enhanced barrier properties of polymer nanocomposite coatings using functionalized carbon nanotubes. Journal of Applied Polymer Science, 138(5), 49621. https://doi.org/10.1002/app.49621 DOI: https://doi.org/10.1002/app.49621

Rashid, A. B., Haque, M., Islam, S. M., & Labib, K. R. U. (2024). Nanotechnology-enhanced fiber-reinforced polymer composites: Recent advancements on processing techniques and applications. Heliyon, 10(2), 1-29. https://doi.org/10.1016/j.heliyon.2024.e24692 DOI: https://doi.org/10.1016/j.heliyon.2024.e24692

Ruvira, B., García-Fayos, B., Juste, B., Arnal, J. M., & Verdú, G. (2022). Experimental estimation of the diffusion coefficient in radon barrier materials based on ISO/TS 11665-13: 2017. Radiation Physics and Chemistry, 193, 109993. https://doi.org/10.1016/j.radphyschem.2022.109993 DOI: https://doi.org/10.1016/j.radphyschem.2022.109993

U.S. Environmental Protection Agency (EPA). (2024). A Citizen’s Guide to Radon: The Guide to Protecting Yourself and Your Family from Radon. EPA 402/K-23/002. https://www.epa.gov/sites/default/files/2016-12/documents/2016_a_citizens_guide_to_radon.pdf

Veselska, O., Vaidya, S., Llido, O., Macko, M., Deroche, I., Bourrelly, S., & Busto, J. (2025). Exploring the science of radon adsorption: Materials, methodologies, and emerging directions. Separation and Purification Technology, 134640. https://doi.org/10.1016/j.seppur.2025.134640 DOI: https://doi.org/10.1016/j.seppur.2025.134640

World Health Organization (WHO). (2023). Radon and Health: Key Facts. Retrieved from https://www.who.int/news-room/fact-sheets/detail/radon-and-health

Author Biographies

Aisha Dalila Ab Aziz, Malaysian Nuclear Agency, Bangi

Author Origin : Malaysia

Mohd Hamzah Harun, Malaysian Nuclear Agency, Bangi

Author Origin : Malaysia

Izzuddin Mohamad Zaharuddin, Malaysian Nuclear Agency, Bangi

Author Origin : Malaysia

Nor Adnin Ezani Mohd Ezani, Malaysian Nuclear Agency, Bangi

Author Origin : Malaysia

Norfazlinayati Othman, Malaysian Nuclear Agency, Bangi

Author Origin : Malaysia

Mahathir Mohamed, Malaysian Nuclear Agency, Bangi

Author Origin : Indonesia

Mohd Faizal Abd Rahman, Malaysian Nuclear Agency, Bangi

Author Origin : Malaysia

Khairil Nor Kamal Umar, Malaysian Nuclear Agency, Bangi

Author Origin : Malaysia

Nurul Huda Mudri, Malaysian Nuclear Agency, Bangi

Author Origin : Malaysia

Khairul Azhar Abdul Halim, Malaysian Nuclear Agency, Bangi

Author Origin : Malaysia

Mohamad Syahiran Mustafa, Malaysian Nuclear Agency, Bangi

Author Origin : Malaysia

Lakam Mejus, Malaysian Nuclear Agency, Bangi

Author Origin : Malaysia

Faizal Azrin Abdul Razalim, Malaysian Nuclear Agency, Bangi

Author Origin : Malaysia

Rosley Che Ismail, Malaysian Nuclear Agency, Bangi

Author Origin : Malaysia

Abdul Muiz Mohd Sani, Malaysian Nuclear Agency, Bangi

Author Origin : Malaysia

Sharilla Mohd Faisal, Malaysian Nuclear Agency, Bangi

Author Origin : Malaysia

Rida Tajau, Malaysian Nuclear Agency, Bangi

Author Origin : Malaysia

How to Cite

Aziz, A. D. A., Harun, M. H., Zaharuddin, I. M., Ezani, N. A. E. M., Othman, N., Mohamed, M., … Tajau, R. (2025). Characterization of Photocurable Functionalized-CNT Nanocoating to Mitigate the Naturally Emission of Radon Gas. Journal of Material Science and Radiation, 1(3), 104–110. https://doi.org/10.56566/jmsr.v1i3.480

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